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Local Rigidity by Flexibility: Unusual Design for Organic THz-Device Materialsby Dong-Joo Kim, In Cheol Yu, Mojca Jazbinsek, Chaeyoon Kim, Woojin Yoon, Hoseop Yun, Sang-Wook Kim, Dongwook Kim, Fabian Rotermund, O-Pil KwonAdvanced Optical Materials 2023, 11(21), 2300807; https://doi.org/10.1002/adom.202300807AbstractTerahertz (THz) waves interact with molecular phonon vibrations of organic matter. When designing organic THz-device materials, conformational flexible groups (CFGs) are in most cases avoided. CFGs create many low-energy conformers with high conformational entropy, which results in large and many phonon vibration modes that lead to undesired self-absorption of THz waves. Here, nonpolar CFGs only having weak intermolecular interaction capability are unusually introduced into organic THz-device materials, utilized for efficient THz wave generation. Newly designed THz-source crystals possess nonpolar methylene (CH2)n units having high conformational flexibility. Compared to previously reported benchmark crystals without methylene CFGs, introducing methylene CFGs significantly reduces void volume in newly designed crystals. This leads to the suppression of molecular phonon vibrations below 2.0 THz (i.e., introducing flexibility results in local rigidity). At infrared pump wavelengths, new CFG-contained crystals generate a strong THz electric field that is one order of magnitude stronger than that generated in inorganic ZnTe crystals. CFG-contained crystals exhibit a flatter spectral shape of the generated THz wave than benchmark crystals without methylene CFGs. Therefore, the introduction of CFGs is a very intriguing design strategy for organic THz-device materials to reduce the limitations caused by phonon vibrations.
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Ir(tri-N-Heterocyclic Carbene)-Catalyzed Production of Hydrogen and Cn Acids from Ethylene Glycolby Mi-hyun Lee, Heemin Byeon, Siwon Kim, Woojin Yoon, Juneseo Park, Hoseop Yun, Sungju Yu, and Hye-Young JangACS Sustainable Chem. 2023, 11(24), 8901–8907; https://doi.org/10.1021/acssuschemeng.3c00950AbstractNovel tri-N-heterocyclic carbene (triNHC)-coordinated iridium catalysts (Ir(triNHC)) were employed for generating clean hydrogen and useful Cn acids from biomass-derived alcohols. The high efficiency and fast rate of hydrogen production (maximum turnover frequency = 13,080 h–1 and 485 L of H2/g-cat·h) from sustainable ethylene glycol were elucidated by the increased electron-richness of Ir(triNHC) complexes where three NHC ligands were coordinated to an iridium(I) ion. Elaborated mechanistic studies support the proposed reaction mechanisms forming H2 and Cn acids. This Ir(triNHC)-catalyzed process converting sustainable alcohols to useful fuels and chemicals is a promising carbon-neutral process.Keywords: sustainable; H2 production; α-hydroxy acid; ethylene glycol; tri-carbene
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In-plane mixed-dimensional 2D/2D/1D MoS2/MoTe2/Mo6Te6 heterostructures for low contact resistance optoelectronicsby Hyeonkyeong Kim, Young Chul Kim, Yeong Hwan Ahn, Youngdong YooChemical Engineering Journal 2023, 468, 143678; https://doi.org/10.1016/j.cej.2023.143678AbstractMixed-dimensional heterostructures formed by combining 2D materials and other dimensional (0D, 1D, and 3D) materials provide new opportunities for various applications owing to their novel properties. However, in-plane mixed-dimensional heterostructures have been rarely investigated. Here, we report a novel flux-controlled chemical vapor deposition method for synthesizing in-plane mixed-dimensional heterostructures composed of monolayer MoS2 and low-dimensional Mo/Te compounds. By adjusting the Te flux and growth time, we controlled the composition, dimension, and phase of the Mo/Te compounds interfaced with the MoS2. While in-plane 2D/1D MoS2/Mo6Te6 and 2D/2D/1D MoS2/2H MoTe2/Mo6Te6 heterostructures were obtained with a low Te flux, in-plane 2D/2D MoS2/mixed 2H-1T’ MoTe2 and 2D/2D MoS2/2H MoTe2 heterostructures were synthesized with a high Te flux. We investigated the transport properties of the devices fabricated with in-plane mixed-dimensional 2D/2D/1D MoS2/2H MoTe2/Mo6Te6 heterostructures and imaged localized electronic band structures using scanning photocurrent microscopy. Under the low bias condition, the device exhibited an Ohmic-like behavior, which has not been achieved in conventional devices with stacked van der Waals junctions. Under the high bias condition, the device showed a rectifying behavior because of band-bending formed at the heterojunctions; this is consistent with the electronic band-alignment expected from the bandgap and electron affinity of the materials.Keywords: MoS2; MoTe2; Mo6Te6; Mixed-dimensional heterostructures; Edge contact
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Temperature Matters: Bacterial Response to Temperature Changeby Seongjoon Moon, Soojeong Ham, Juwon Jeong, Heechan Ku, Hyunhee Kim & Changhan LeeJournal of Microbiology 2023, 61, 343–357; https://doi.org/10.1021/acsaem.3c00130AbstractTemperature is one of the most important factors in all living organisms for survival. Being a unicellular organism, bacterium requires sensitive sensing and defense mechanisms to tolerate changes in temperature. During a temperature shift, the structure and composition of various cellular molecules including nucleic acids, proteins, and membranes are affected. In addition, numerous genes are induced during heat or cold shocks to overcome the cellular stresses, which are known as heat- and cold-shock proteins. In this review, we describe the cellular phenomena that occur with temperature change and bacterial responses from a molecular perspective, mainly in Escherichia coli.Keywords: Heat shock; Cold shock; Thermosensor; Heat shock protein; Chaperone; Cold shock protein
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Plasma Surface Modification of 3Y-TZP at Low and Atmospheric Pressures with Different Treatment Times by Sung Un Kang, Chul-Ho Kim, Sanghyun You, Da-Young Lee, Yu-Kwon Kim , Seung-Joo Kim, Chang-Koo Kim, Hee-Kyung Kim International Journal of Molecular Sciences 2023, 24(8), 7663; https://doi.org/10.3390/ijms24087663 AbstractThe efficiency of plasma surface modifications depends on the operating conditions. This study investigated the effect of chamber pressure and plasma exposure time on the surface properties of 3Y-TZP with N2/Ar gas. Plate-shaped zirconia specimens were randomly divided into two categories: vacuum plasma and atmospheric plasma. Each group was subdivided into five subgroups according to the treatment time: 1, 5, 10, 15, and 20 min. Following the plasma treatments, we characterized the surface properties, including wettability, chemical composition, crystal structure, surface morphology, and zeta potential. These were analyzed through various techniques, such as contact angle measurement, XPS, XRD, SEM, FIB, CLSM, and electrokinetic measurements. The atmospheric plasma treatments increased zirconia’s electron donation (?−) capacity, while the vacuum plasma treatments decreased ?− parameter with increasing times. The highest concentration of the basic hydroxyl OH(b) groups was identified after a 5 min exposure to atmospheric plasmas. With longer exposure times, the vacuum plasmas induce electrical damage. Both plasma systems increased the zeta potential of 3Y-TZP, showing positive values in a vacuum. In the atmosphere, the zeta potential rapidly increased after 1 min. Atmospheric plasma treatments would be beneficial for the adsorption of oxygen and nitrogen from ambient air and the generation of various active species on the zirconia surface.Keywords: plasma gases; zirconium oxide; surface properties; atmospheric pressure; vacuum
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- 작성일2024-01-16
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Reformulating land-use regression method as sign-constrained regularized regressions: Advantages and improvementsby Soon-Sun Kwon, Hosik Choi, Whanhee Lee, Yeonjin Kim, Hwan-Cheol Kim, Woojoo LeeEnvironmental Modelling & Software 2023, 11(12), 105653; https://doi.org/10.1016/j.envsoft.2023.105653AbstractLand-use regression is a popular method for predicting ambient pollutant concentrations at points of interest where no measurements are taken. However, the model-building process is complicated, and systematically understanding when and how the process works is difficult. To overcome these limitations, we reformulate the existing land use regression method as a sign-constrained regression problem with an explicit objective function to be minimized. This novel formulation always leads to estimated regression coefficients that satisfy the predefined direction based on subject matter knowledge while simultaneously substantially improving the prediction performance of the existing land-use regression method. The advantages of the proposed sign-constrained regression method are confirmed through a numerical study and real data analysis.Keywords: Land use regression; Sign constraints; Penalized regression methods; Prediction; Interpretability
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Large‐Area Structure‐Selective Synthesis of Symmetry‐Broken MoSe2 and Their Broadband Nonlinear Optical Responseby Joohyeon Ahn, Seongju Ha, Jungseok Choi, Dong‐Il Yeom, Youngdong YooAdvanced Optical Materials 2023, 11(12); https://doi.org/10.1002/adom.202203116AbstractTransition metal dichalcogenides (TMDCs) have various electronic and optical properties depending on their structure, so they can be used as a fascinating material in various applications including photonics, electronics, optoelectronics, and valleytronics. In particular, spiral TMDCs grown through the formation of screw dislocations exhibit novel electronic and optical properties different from layer-by-layer TMDCs. However, large-area structure-selective synthesis of TMDCs remains challenging. Here, this work reports for the first time the large-area structure-selective synthesis of monolayer MoSe2 and spiral MoSe2 using a flux-controlled chemical vapor deposition method. Under a low MoSe2 flux condition, monolayer MoSe2 is synthesized, whereas thick spiral MoSe2 is synthesized under a high flux condition. Under a medium flux condition, both monolayer and spiral MoSe2 are synthesized. In addition, through the nonlinear optical (NLO) signal analysis of monolayer MoSe2 and spiral MoSe2, the giant enhancement of NLO signals induced by the combined effect of breaking inversion symmetry and the excitonic resonance effects in the synthesized MoSe2 is confirmed. Monolayer MoSe2 and spiral MoSe2 synthesized using this method are expected to be used as advanced optical materials for novel electronics, optoelectronics, and NLO applications.
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Special Issue on Nano-Electronic Devices and Functional Applicationsby Chuljin Hwang and Sungjun Parkapplied science 2023, 13(11), 6692; https://doi.org/10.3390/app13116692Nano-electronic devices and materials hold considerable promise due to their inherent structural and material benefits, such as device miniaturization, increased integration density, and reduced power consumption. Streamlined techniques for nano-scale fabrication of these devices and materials, which are compatible with large-scale production and solution processes, help us to further understand their operational mechanisms or their respective formation processes. These advancements have resulted in significant breakthroughs in functional electronic devices, including light-emitting diodes, photodetectors, photovoltaics, transistors, and sensors. In addition, devices that feature flexibility and stretchability offer unprecedented performance for user-friendly electronic applications. This Special Issue is dedicated to discussing the most recent advancements and trends in nano-electronic devices and materials research. It includes a total of seven papers—five original research articles and two review articles as follows.
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